Laser induced multi-component luminescence of [CuNCS(1,10-phen)P(CH2N(CH2CH2)2O)3]-the first example of CuNCS complexes with diimines and tris(aminomethyl)phosphanes

► A new Cu(I) complex with tris(aminomethyl)phosphine morpholine is presented. ► An X-ray structure of this complex is characterized. ► Solid state luminescence spectra of this complex show several MLLCT bands.