کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5415526 | 1393762 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The molecular symmetry group of the CO dimer and the assignments of the intermolecular vibrations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Vibrational assignments for some of the lowest energy levels of the CO dimer have been derived purely spectroscopically on the basis of the molecular symmetry, nuclear spin statistics, observed selection rules, and sequence of the transition doublets. Most of the previous assignments of Surin et al. [L.A. Surin, D.N. Fourzikov, T.F. Giesen, S. Schlemmer, G. Winnewisser, V.A. Panfilov, B.S. Dumesh, G.W.M. Vissers, A. van der Avoird, J. Phys. Chem. A 111 (2007) 12238-12247] are confirmed in the present work, and are supported by much clear evidences. One significant revision of that analysis in the present work is identification of the torsional (out-of-plane) excited state, which had been assigned previously to an excited state of the geared (in plane) internal rotation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 254, Issue 2, April 2009, Pages 87-93
Journal: Journal of Molecular Spectroscopy - Volume 254, Issue 2, April 2009, Pages 87-93
نویسندگان
Koichi M.T. Yamada,