کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5431740 | 1508823 | 2017 | 8 صفحه PDF | دانلود رایگان |
High specific surface area (SSA), especially effective specific surface area (E-SSA) of the active electrode materials is required for high performance supercapacitors. In this work, such materials (e.g. AC-KOH) were obtained using a scalable industrial method from biomass waste material, with controlling the pore size distribution and mesopores as the major contribution. Thus, an electrode material, with ultrahigh mesopore volume of 1.85 cm3 gâ1, E-SSA up to 1771 m2 gâ1 for organic electrolyte ion (TEA+) and taking 55% of the total SSA of 3237 m2 gâ1 with an excellent conductivity of 33 S mâ1, was obtained. With these outstanding properties, the materials demonstrate excellent double-layer capacitance with remarkable rate performance and good cycling stability. The material delivers capacitance up to 222, 202 and 188 F gâ1 at current density of 1 A gâ1 in aqueous, organic and ionic liquid electrolyte system, respectively. Meanwhile, it exhibits a high energy density of 80 W h kgâ1 in ionic liquid electrolyte at a power density of 870 W kgâ1. Furthermore, these materials can be produced in large scale from various biomass materials, and thus could be an excellent choice of the high performance materials required in the increasing important supercapacitor industry.
An electrode material (AC-KOH) with ultrahigh effective specific surface area up to 1771 m2 gâ1 for organic electrolyte ion (TEA+), taking 55% of the total specific surface area of 3237 m2 gâ1, mesopore volume of 1.85 cm3 gâ1 with 81.5% proportion of the total pore volume of 2.27 cm3 gâ1 and excellent conductivity of 33 S mâ1 was obtained. AC-KOH based supercapacitor delivers capacitance up to 222, 202 and 188 F gâ1 at current density of 1 A gâ1 in aqueous, organic and ionic liquid electrolyte system, respectively. Meanwhile it exhibits high energy density of 80 W h kgâ1 in ionic liquid electrolyte at power density of 870 W kgâ1, superior than that of commercial activated carbon YP50. AC-KOH based coin-type supercapacitor could lighten a red LED and make it light up for â¼30 min.255
Journal: Carbon - Volume 124, November 2017, Pages 64-71