کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5435342 1509346 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Luminophore from forgotten dye: di(Alkylthiophene) derivative of benzo[h]benz[5,6]acridino[2,1,9,8-klmna]acridine
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد بیومتریال
پیش نمایش صفحه اول مقاله
Luminophore from forgotten dye: di(Alkylthiophene) derivative of benzo[h]benz[5,6]acridino[2,1,9,8-klmna]acridine
چکیده انگلیسی


- A new luminophore: di(alkylthiophene) derivative of flavanthrone (FTC8) was synthesized.
- The FTC8 showed very high photoluminescence QY (60%) value.
- Molecules of FTC8 have a strong tendency to self-organize in monolayers deposited on the surface of HOPG, as observed by STM.

A new, solution processable and highly luminescent compound (photoluminescence QY ca. 60%), namely di(alkylthienyl) substituted benzo[h]benz[5,6]acridino[2,1,9,8-klmna]acridine, abbreviated as (FTC-8) was synthesized. FTC-8 is electrochemically active showing a quasi-reversible redox couple at negative potentials (vs Fc/Fc+) and an irreversible oxidation peak at positive ones. Its ionization potential and electron affinity values, determined from the cyclic voltammetry results are: IP = 5.48 eV and ǀEAǀ = 3.36 eV. The effect of the conjugation extension from the azaacene core to alkylthienyl substituent on the electrochemical and spectroscopic properties of FTC-8 is rather weak, which is consistent with DFT calculation showing that the core and the thienyl substituent are almost orthogonal. Taking into account the measured redox properties and efficient luminescence, FTC-8 can be considered as a promising candidate for the fabrication of light emitting diodes. FTC-8 shows also strong tendency to self-assemble forming highly ordered monolayers on HOPG graphite as demonstrated by STM investigations.

167

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 232, October 2017, Pages 117-122
نویسندگان
, , , , ,