کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5436893 1509654 2017 20 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Geopolymerization reaction, microstructure and simulation of metakaolin-based geopolymers at extended Si/Al ratios
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی صنعتی و تولید
پیش نمایش صفحه اول مقاله
Geopolymerization reaction, microstructure and simulation of metakaolin-based geopolymers at extended Si/Al ratios
چکیده انگلیسی
Metakaolin-based geopolymers were synthesized at Si/Al ratios of 1:1, 1.5:1, 2:1, 3:1, 4:1, and 5:1 by using silica fume as silica corrector to alter Si ratios. The microstructure and strength of these geopolymers were characterized through XRD, SEM, NMR and compressive strength measurements. The dissolving rates of Al and Si species in geopolymerization were measured, and freeze-dried N-A-S-H gel was characterized by FTIR spectra. Modelling and simulation were employed to calculate the binding energy of one Si atom and the total energy of geopolymers formed at various Si/Al ratios. At Si/Al ratio of 2:1, high concentrations of Si and Al species are dissolved from precursors, high contents of Si-O-T linkages are formed and the geopolymer is of high compressive strength. The mechanical strength of geopolymers at various Si/Al ratios is dependent on the formation of N-A-S-H gel, rather than the zeolitic nuclei or silicate derivatives. This study might provide fundamentals for the geopolymerization of mine tailings, which usually possess high Si/Al ratios.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Cement and Concrete Composites - Volume 79, May 2017, Pages 45-52
نویسندگان
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