کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5441538 1510389 2017 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Formation and structural analysis of 15MgO-15CaO-8P2O5-4SiO2 glass
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Formation and structural analysis of 15MgO-15CaO-8P2O5-4SiO2 glass
چکیده انگلیسی
MgO-CaO-P2O5-SiO2 invert glass in the orthophosphate region was successfully prepared using a melt-quenching method, and its structure and dissolution behavior were evaluated. The 31P and 29Si solid-state nuclear magnetic resonance and Raman spectroscopies showed that the glass structure consisted of orthophosphate (Qp0) and orthosilicate (QSi0) tetrahedra cross-linked by cations such as Mg2 + and Ca2 + ions; there were no chain phosphate groups and silicate network structures. MgO present in the glass acts as an intermediate oxide that cross-links Qp0 and QSi0, thereby imparting excellent glass-forming ability. Mg2 + and Ca2 + ions present in the glass were preferentially bonded with silicate and phosphate groups to form SOMg and POCa bonds, respectively. The ions-releasing amount from the glass was higher than that from previously reported phosphate invert glasses.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 457, 1 February 2017, Pages 73-76
نویسندگان
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