|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|5462821||1398820||2017||4 صفحه PDF||سفارش دهید||دانلود کنید|
- A novel iridium porphyrin was synthesized.
- It is proposed the stabilization of the porphyrin sphere with axial ligands.
- Confirmation of iridium complex stability by spectroscopic techniques.
The novel iridium-pentafluorophenyl porphyrin complex (TPFPPIrCl(CO)) was successfully synthesized by chemical reaction with the iridium (I) metal precursor [Ir(COD)Cl]2. The final complex was identified linked to the axial Cl and CO ligands by UV-Visible, 1H, 13C NMR spectroscopy as well the 1H/13C correlated techniques and by mass spectrometry.
Journal: Materials Letters - Volume 200, 1 August 2017, Pages 6-9