کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5468627 1519047 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Adsorptive removal of 134Cs+, 60Co2 + and 152 + 154Eu3 + radionuclides from aqueous solutions using sepiolite: Single and multi-component systems
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات ژئوشیمی و پترولوژی
پیش نمایش صفحه اول مقاله
Adsorptive removal of 134Cs+, 60Co2 + and 152 + 154Eu3 + radionuclides from aqueous solutions using sepiolite: Single and multi-component systems
چکیده انگلیسی
Single and multi-component adsorptive removal of 134Cs+, 60Co2 + and 152 + 154Eu3 + from aqueous solutions onto sepiolite are studied in the present study. Removal of these radionuclides in single systems is found to be strongly dependent on the initial pH on the solution. Removals > 99% (for 60Co2 + and 152 + 154Eu3 +) and of about 82% (for 134Cs+) are achieved at initial pH values higher than 4 and 5, respectively. The kinetic data and the equilibrium isotherms are modeled by two kinetic models, the pseudo-first-order and the pseudo-second-order, and two isotherm models, Langmuir and Freundlich, respectively. The effect of various coexisting cations, Na+, Ca2 + and Al3 +, at different concentrations on the adsorption processes of the concerned radionuclides in single systems was evaluated. Desorption studies of radionuclide-loaded sepiolite are studied using different concentrations of organic, EDTA and HA (strong complexing agents for radionuclides), and inorganic, HCl, NaCl, CaCl2, Mg(NO3)2 and AlCl3, desorbing agents. Adsorption mechanisms of radionuclides onto sepiolite are deeply discussed. Multi-component adsorptive removal of 134Cs+, 60Co2 + and 152 + 154Eu3 + onto sepiolite as a function of adsorbent weight and time was also studied. The influence of the solution pH on co-removal efficiency of radionuclides was investigated in presence of EDTA. Furthermore, the present investigation evaluated the removal efficiency of radionuclides, in multi-systems, in presence of different concentrations either of NaCl or CaCl2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Clay Science - Volume 141, 1 June 2017, Pages 72-80
نویسندگان
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