کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5491094 1524792 2017 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Annealing temperature dependent non-monotonic d0 ferromagnetism in pristine In2O3 nanoparticles
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Annealing temperature dependent non-monotonic d0 ferromagnetism in pristine In2O3 nanoparticles
چکیده انگلیسی


- Effect of air-annealing temperature on the d0 ferromagnetism of pure In2O3.
- Oxygen-deficiency states of all samples were detected by Raman scattering and PL.
- Ferromagnetism changes non-monotonically with the increasing annealing temperature.
- d0 ferromagnetism in our In2O3 nanoparticles is related with the surface VO+.

Cubic bixbyite In2O3 nanoparticles with room temperature d0 ferromagnetism were prepared by sol-gel method with the air annealing temperature ranging from 500 to 900 °C. X-ray diffraction, X-ray photoelectron spectroscopy, Raman-scattering and photoluminescence were carried out to demonstrate the presence of oxygen vacancies. The lattice constant, the atomic ratio of crystal O and In, the Raman peak at 369 cm−1, the PL emission peak at 396 nm and the saturation magnetization of d0 ferromagnetism all had a consistent non-monotonic change with the increasing annealing temperature. With further considering the relation between the grain size and the distribution of oxygen vacancies, we think that d0 ferromagnetism in our samples is directly related with the singly charged oxygen vacancies at the surface of In2O3 nanoparticles.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 429, 1 May 2017, Pages 69-73
نویسندگان
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