Influence of seasonality and vegetation on the attenuation of emerging contaminants in wastewater effluent-dominated streams. A preliminary study

- The attenuation of ECs 1 km downstream ranged from no removal to up to 80%.
- The half-lives of ECs in the 4 streams ranged from 0.4 to 20 h (3.9 ± 3.5 h).
- The in-stream attenuation of ECs showed a high seasonality.
- The stream covered by vegetation had the shortest half-lives for most of the ECs.
- All streams were capable of decreasing the cumulative acute HQ 1 km downstream.

Treated wastewater from small communities is discharged into rivers or streams with a high biodiversity value. This is particularly important in Mediterranean countries, where most of the streams are dry almost all year round. This preliminary study assessed the occurrence and attenuation of 23 emerging contaminants (ECs) in 4 wastewater-dominated streams in which treated wastewater accounted for the entire stream flow. The concentration of ECs was monitored in the warm and cold seasons in the wastewater treatment plant (WWTP) effluent and at 6 downstream locations. The concentration of ECs in the WWTP effluents ranged from undetected to 12 μg L−1. The attenuation of ECs 1 km downstream ranged from no removal to up to 80% (48% on average). The half-lives of ECs in the 4 streams ranged from 0.4 to 20 h (3.9 ± 3.5 h on average). Compounds such as benzodiazepine drugs and flame retardants were the most recalcitrant (half-lives >5 h). The highest attenuation of ECs and ammonia was observed in the stream completely covered by vegetation. The cumulative hazardous quotient 1 km downstream was reduced on average by more than 60%. Therefore, the results suggest that both seasonality and vegetation play an important role in in-stream attenuation of ECs.

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