Effect of cosolvents in the presence of sodium dodecyl sulfate micelles on the rate of alkaline hydrolysis of tris(2,2′-bipyridine)iron(II) complex

• Effect of alcohols, SDS and their mixture on alkaline hydrolysis of Fe(II) complex.
• Fe(II) complex-SDS binding inhibits the rate of reaction.
• 1-Alkanols catalyze the reaction rate both in presence and absence of SDS.
• Glycols have almost no effect in the presence of SDS but reduce the rate in absence of it.
• 1-Alkanols reduce Fe(II) complex-SDS binding more effectively than glycols.

The kinetics of alkaline hydrolysis of tris(2,2′-bipyridine)iron(II) complex have been studied in the presence of various alcohols of different chain lengths and number of OH groups in aqueous and SDS micellar medium. In aqueous medium, rate increases at all percentages of 1-alkanols in the following order: PrOH > EtOH > MeOH > H2O, whereas the effectiveness of glycols as inhibitors is in the following order: Gly > EG > PG > H2O. Hence PrOH has the most pronounced effect as accelerator and Gly as inhibitor on rate. In the presence of SDS micelles, rate has been inhibited because of binding of SDS with substrate, but the presence of alcohols reduces this inhibitory effect of SDS. All these results have been explained in terms of the CMC, micellar size and properties of SDS in these cosolvents, H-bonding capacity of solvents, dielectric constants of the media, etc.

Figure optionsDownload as PowerPoint slide