Mercury in Baltic Sea sediments-Natural background and anthropogenic impact

In total 27 short and one long sediment core, and 278 surface sediment samples from the Baltic Sea were analyzed for mercury (Hg), and organic carbon contents. Thirteen short cores and the long core were dated by radionuclide methods (210Pb, 137Cs, AMS14C). The dataset allows discriminating between natural and human induced changes on the Hg levels in Baltic Sea sediments. Preindustrial Holocene background concentrations vary between 20 and 50 μg Hg per kg dry sediment and are positively correlated with organic carbon changes. Strong human induced pollution is recorded for the second half of the past century and caused high Hg concentrations of up to several hundred μg Hg per kg dry sediment even in Baltic Sea basins. Maximum concentrations are found at industrial and war waste dumping sites (local hot spots). An Hg concentration decreasing trend toward the present day is observed at most coring sites, a result of environmental measures undertaken during the last two decades. At sites where it is possible to calculate Hg fluxes, the natural accumulation rates vary between 2.1 and 5.4 μg Hg per m2 per year. Anthropogenically sourced Hg accumulation rates vary in a wide range of 30 and 300 μg Hg per m2 per year for the time span of maximum pollution. In areas characterized by discontinuous sedimentation only “inventories” of human sourced Hg expressed as the total amount of deposited Hg (above the natural background) per m2 can be calculated. The inventories of the investigated cores vary in the range of 1 and 8 mg Hg per m2. Additionally, influences of sediment dynamics on spatial distribution pattern of Hg concentrations in surface and subsurface sediments are discussed.