کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
639771 | 1456949 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improved capacitive deionization performance by coupling TiO2 nanoparticles with carbon nanotubes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this paper, TiO2 nanoparticles (NPs) were exploited with carbon nanotube (CNTs) to form a composite electrode (TiO2/CNTs) for capacitive deionization (CDI). The phase morphology, crystal and electronic structure were characterized by scanning electron microscopy, Transmittance electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy, respectively. The electrochemical behavior was carried out by cyclic voltammetry. Furthermore, the desalination performances of TiO2/CNTs composite electrode were investigated at different electrical voltages and ionic strengthen in a batch mode operation. The results demonstrated that the TiO2/CNTs electrode prepared from 1Â wt% TiO2 NPs (TiO2/CNTs-1) exhibits the best results compared to other electrodes having 2 and 5Â wt% TiO2 NPs. Remarkably, the best electrode showed high specific capacitance (122Â F/g) at 1Â mV/s in 1Â M KCl solutions and excellent electrosorptive capacity (4Â mg/g) predicted from Langmuir isotherm which is nearly twice higher than that of pristine CNTs electrode. Moreover, the electrosorption follows the pseudo first adsorption kinetics and the proposed electrode shows interesting recyclability and easy full regeneration.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 171, 17 October 2016, Pages 93-100
Journal: Separation and Purification Technology - Volume 171, 17 October 2016, Pages 93-100
نویسندگان
Haibo Li, Yulong Ma, Rui Niu,