On the apparent visible-light and enhanced UV-light photocatalytic activity of nitrogen-doped TiO2 thin films

- Synthesis of NTiO2 films using atmospheric-pressure CVD and different N precursors.
- Sensitisation of NTiO2 films by surface N groups under UVA irradiation.
- Deactivation of NTiO2 films by surface NO species.
- Discussion on the apparent visible light activity of NTiO2 thin films.

Nitrogen-doped titania (NTiO2) thin films were synthesized using atmospheric-pressure chemical vapor deposition (APCVD) using ammonia, tert-butylamine or benzylamine as the nitrogen source. The influence of these precursors on the structural, morphological and optical absorption properties of the films was studied using X-ray diffraction (XRD), Raman spectroscopy, Scanning electron microscopy (SEM) and UV/Vis spectroscopy. The chemical state and location of the nitrogen species in the films was investigated using X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of films with similar structural properties was evaluated during degradation of stearic acid under UVA and visible light illumination. A previous study established a potential photosensitization mechanism involving surface N groups with binding energy of ∼400 eV, which would result in extrinsic enhanced UV activity of the NTiO2 films. Here, an empirical approach was adopted in order to establish correlation between structural features, nitrogen content and photocatalytic properties of these films. Within the thickness range considered, the photocatalytic activities of the undoped TiO2 films were consistent with their diffraction features (peak intensities and sharpness). Nevertheless, the activities of the NTiO2 films did not follow the same trend but it was consistent with their nitrogen content. Further evidence is provided on the participation of nitrogen species on the enhanced UV activity of NTiO2 films and the impact of surface NO groups such as NOTiO (or ONTiO) and bulk substitutional nitrogen groups is discussed. Discussion is also provided on the apparent visible light activity of the NTiO2 films.