کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6456158 | 1419841 | 2017 | 9 صفحه PDF | دانلود رایگان |
- Bicyclic guanidines for the chemical fixation of CO2 into linear and cyclic ureas.
- One-pot synthesis of imidazolidinones from propargylamines, primary amines and CO2.
- Control experiments and crystallographic findings support the proposed pathways.
- Metal-, ligand-, VOCs- and isocyanate-free protocol for the synthesis of ureas.
- An easily scalable process.
A novel methodology to easily access imidazolidin-2-ones from propargylamines, primary amine and CO2 with TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene) or MTBD (7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene) as catalysts under solvent-free conditions is here reported. Bicyclic guanidines, able to catalyze the formation of oxazolidinones from secondary propargylamines and CO2, are now presented for the first time as effective organocatalysts for the chemical fixation of CO2 into linear and cyclic ureas. Plausible reaction pathways are proposed on the basis of experimental findings.
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Journal: Journal of CO2 Utilization - Volume 21, October 2017, Pages 553-561