Recovery of monoethylene glycol combined with kinetic hydrate inhibitor

- The recovery rate of MEG was affected by the temperature rather than HI-121.
- HI-121 could be recovered along with MEG under proper recovery conditions.
- HI-121 with various polymer chain lengths reduced the TIE of the recovered MEG.
- The solution recovered under milder conditions retained good inhibitory performance.
- Adding 5 wt% MEG restored the recovered solution performance to original levels.

Kinetic hydrate inhibitors (KHIs) combined with thermodynamic inhibitors (THIs) such as monoethylene glycol (MEG) have been good additives for the prevention of hydrate blockages in oil and gas industry operations. The regeneration and recycling of MEG are conventional process steps used to reduce costs. However, the recovery of THIs in the presence of KHIs or the recovery of the KHIs alone has rarely been investigated. In this paper, a series of experiments was designed to study the recovery of both a KHI based poly (N-vinylcaprolactam) and MEG. The results showed that the MEG recovery rate was closely related to the recovery temperature, but was not influenced by the KHI. The MEG recovery rate from solutions consisting of MEG and the KHI was as high as 94.52%, and the KHI was recovered along with the MEG. The polymer structure of the KHI was rarely changed when the recovery temperature was close to its polymerization temperature. The presence of the KHI had a negative impact on the thermodynamic inhibition efficiency of the MEG. The KHI performance of the recovered solution obtained at the KHI polymerization temperature could reach the level of the fresh combination inhibitor, but the recovered solutions obtained at temperatures far above the KHI polymerization temperature demonstrated worse inhibitory performance. The kinetic performance could be restored by adding 5.0 wt% fresh MEG. MEG enabled a subcooling temperature decrease into the range in which KHI which could play its role effectively, leading to the improved kinetic performance of the recovered solution.

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