کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6469563 | 1423975 | 2017 | 4 صفحه PDF | دانلود رایگان |
- An intramolecular electron transfer from an amine to a ferricenium moiety is demonstrated.
- A ferrocenyl 'antenna' makes it possible to graft an amino compound at low anodic potential.
- Preparation of surface molecular assemblies of unsaturated bridged ferrocenyl moieties.
Two aminoferrocene complexes were studied by electrochemical techniques. Molecules retain the redox properties of both ferrocene and amine groups, but fundamentally different behaviours were observed depending on whether the linker between the two redox end groups was saturated (ethyl bridge) or not (ethynyl bridge). The possibility of an intramolecular electron transfer from the amine to the ferricenium moiety through the Ï-conjugated linker was demonstrated and the ethynyl bridge is expected to have a dual effect by facilitating both the oxidation of the amine into the cation radical and the production of aminyl radical, due to its strong electron withdrawing effect. Because of this synergy of properties, grafting of the conjugated aminoferrocene complex can occur just by oxidizing the ferrocene group without the presence of a base in solution.
Journal: Electrochemistry Communications - Volume 82, September 2017, Pages 52-55