کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6473680 | 1424964 | 2017 | 11 صفحه PDF | دانلود رایگان |
- Catalysts of cobalt supported on modified KIT-6 silica were prepared and applied to oxidative desulfurization (ODS).
- A novel Co/KIT-6 catalysis system was developed and evaluated with better DBT removal.
- Response surface methodology was used to optimized the main variables for Co/KIT-6 catalytic ODS system.
- Kinetics of ODS correlated well with the pseudo-first-order equation.
Sulfur-containing compounds in oils are harmful to the ecosystem whose cost-effective removal is still a challenge. In this study, novel heterogeneous catalysts of cobalt supported on KIT-6 mesoporous silicas were prepared and evaluated for oxidative desulfurization (ODS) under ambient conditions using cyclohexanone peroxide (CYHPO) as the oxidant. The model oil was obtained via dissolving DBT in the n-octane. The conventional wet impregnation method was applied for the preparation of the catalysts, and cobalt nitrate was used as the precursor. The catalysts were characterized by XRD, N2-physisorption, FT-IR, TGA, SEM/TEM and XPS. Then their catalytic activities in total oxidation of dibenzothiophene (DBT) were evaluated at various conditions. DBT conversion by this heterogeneous ODS system reached 98.68%. Co/KIT-6 catalysts showed high ODS activity due to Ia3d mesoporous structure resulting in better cobalt dispersion, higher activity of Co, and faster diffusion of reactant and products. The Box-Behnken design showed that the optimum values for the conversion of DBT were 93 °C (oxidation temperature), 1.6 Ã 10â1 g (catalyst amount) and 5.7 (O/S molar ratio), respectively. The inhibitory effect of quinoline on ODS was higher than carbazole and indole, adding quinoline into model oil under same conditions led to a decrease of the conversion of DBT from 98.68% to 65.67% when the concentration of quinoline increased from 160 ppm to 4845 ppm. Kinetics data correlated well with the pseudo-first-order equation. These data showed that this novel Co/KIT-6 catalysis system has the potential to be applied in ODS from oils.
Journal: Fuel - Volume 200, 15 July 2017, Pages 11-21