کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6474273 | 1424961 | 2017 | 7 صفحه PDF | دانلود رایگان |
- Ag+ and graphene oxide (GO) were co-reduced through simple method.
- The removal efficiency was higher than 99% under the pH of 5.0.
- The co-existed metal ions had hardly impact for the removal.
- The sorbent showed excellent performance of regeneration and reutilization.
A novel Ag/graphene adsorbent was synthesized for the Hg(II) removal from waste water. The Ag/graphene was characterized by Fourier Transformation Infrared Spectrum (FT-IR), X-ray Diffraction (XRD), Transmission Electron Microscope (TEM) and Scanning Electron Microscope (SEM) devices. The results showed that graphene acted as a good support for Ag particles on its huge surface. The removal efficiency of Hg2+ was higher than 98% after 120Â min adsorption. The optimized pH value was 5.0. There are no obvious effects of co-existed metal ions (Mn2+, Mg2+, Ca2+, Al3+ and Na+) on Hg2+ removal. Meanwhile, the adsorption isotherms and adsorption kinetics were applied to analyze the experimental data. The best interpretation was given by Freundlich isotherm equation. The kinetic adsorptions were well described by a pseudo-second-order reaction model. Furthermore, the performance of regeneration and reutilization were also investigated. The results indicated that the adsorption capacity remained stable after 6 reuse cycles.
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Journal: Fuel - Volume 203, 1 September 2017, Pages 128-134