کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6599820 | 458917 | 2016 | 45 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of NIR fluorescent thienyl-containing aza-BODIPY and its application for detection of Hg2+: Electron transfer by bonding with Hg2+
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Utilizing 2-vinylthiophene as the starting material, the thienyl-containing aza-BODIPY 1 was successfully prepared. Aza-BODIPY 1 absorbs at 760Â nm and emits at 782Â nm in CHCl3 in NIR region. Aza-BODIPY 1 as a NIR turn-off chemosensor was highly selective to Hg2+. The fluorescence quenching is due to that the electrons from the thienyl groups to the aza-BODIPY core were transferred after binding with Hg2+. The chemosensor 1 can be used to detect Hg2+ in MCF-7Â cells, indicating its potential application for studying the effect of Hg2+ in biological system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 125, February 2016, Pages 136-141
Journal: Dyes and Pigments - Volume 125, February 2016, Pages 136-141
نویسندگان
Xin-Dong Jiang, Jiuli Zhao, Qian Li, Chang-Liang Sun, Jian Guan, Gao-Tao Sun, Lin-Jiu Xiao,