کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6608485 | 459541 | 2016 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nitrogen-doped graphene enwrapped silicon nanoparticles with nitrogen-doped carbon shell: a novel nanocomposite for lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
A novel nanocomposite (NG/Si@NC) consisting of nitrogen-doped graphene (NG) enwrapped Si nanoparticles (SiNPs) with a nitrogen-doped carbon shell (NC) was prepared as a new anode material for lithium-ion batteries (LIBs). The NG/Si@NC was synthesized by a facile and environmentally friendly solution-mixing and carbonization approach. SEM and TEM confirmed that NC-encircled SiNPs (Si@NC) were evenly anchored on and completely enwrapped by NG. It was found that nitrogen was simultaneously doped into graphene nanosheets and carbon shell on SiNPs. Electrochemical measurements demonstrated the significant role of nitrogen doping in enhancing the electrochemical performance of NG/Si@NC. The NG/Si@NC electrode exhibited a reversible capacity of 938 mAh gâ1 at a current density of 500 mA gâ1 over 100 cycles, which is significantly higher as compared to the nondoped graphene enwrapped SiNPs with a nondoped carbon shell (G/Si@C) (603 mAh gâ1) and graphene enwrapped bare SiNPs (G/Si) (240 mAh gâ1).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 22-29
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 22-29
نویسندگان
Dehui Ji, Yizao Wan, Zhiwei Yang, Chunzhi Li, Guangyao Xiong, Lili Li, Ming Han, Ruisong Guo, Honglin Luo,