کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6616996 | 459625 | 2013 | 46 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Graphene-TiO2 composite supported Pt electrocatalyst for oxygen reduction reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A nano-sized Pt catalyst supported onto titanium dioxide functionalized graphene nanosheets (TiO2-FGSs) was prepared using the polyol method and utilized for a catalyst activity investigation toward the oxygen reduction reaction (ORR). The electrochemical and microscopic studies were carried out using a 40 wt.% Pt/TiO2-FGS catalyst. Cyclic voltammetry and the rotating disk electrode experiments were performed in 0.5 M H2SO4 and 0.1 M KOH solutions in order to investigate the electrocatalytic behavior of the prepared catalysts. The composite catalyst samples were characterized by scanning electron microscopy and transmission electron microscopy showing a good dispersion of the Pt particles on the surface of the graphene supported TiO2 particles. The average Pt particle size was 11 ± 2 nm. The values of specific activity and other kinetic parameters were determined from the Tafel plots taking into account the real electroactive area of each electrode. The electrodes exhibited a relatively high electrocatalytic activity for the four-electron reduction of oxygen to water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 107, 30 September 2013, Pages 509-517
Journal: Electrochimica Acta - Volume 107, 30 September 2013, Pages 509-517
نویسندگان
Kristiina Tiido, Nadezda Alexeyeva, Martin Couillard, Christina Bock, Barry R. MacDougall, Kaido Tammeveski,