کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
672780 | 1459460 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photothermoelectric (PTE) detection of phase transitions. Application to triglycinesulphate (TGS)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A recently introduced photothermal method, the photothermoelectric (PTE) calorimetry is proposed for the first time in order to detect phase transitions. The capability of both back (BPTE) and front (FPTE) detection configurations in detecting phase transitions is analyzed. It was found that the back detection configuration, with optically opaque sample and thermally thick sample and TE sensor, is very suitable for phase transitions detection; the information, in this configuration, can be collected from both amplitude and phase of the BPTE signal and the amplitude has the possibility of amplifying the critical anomaly of the thermal parameters. In the FPTE configuration, the information about phase transition is contained only in the amplitude of the signal. Using the PTE method, the well-known ferro-paraelectric phase transition of triglycinesulphate (TGS), tacking place at about 49 °C, was investigated. Comparison with the photopyroelectric (PPE) method is performed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 624, 20 January 2016, Pages 21-26
Journal: Thermochimica Acta - Volume 624, 20 January 2016, Pages 21-26
نویسندگان
D. Dadarlat, C. Tudoran, V. Surducan, C. Bourgès, P. Lemoine, E. Guilmeau,