Thermodynamic study of binary mixtures of tricyclo[5.2.1.02.6]decane with N-methylpiperazine or triethylamine at T = 298.15–323.15 K

Density and viscosity for binary mixtures of tricyclo[5.2.1.02.6]decane with N-methylpiperazine (NMP) or triethylamine (TEA) have been measured at different temperatures of 298.15, 303.15, 308.15, 313.15 and 323.15 K over the entire composition range. From these densities, all the experimental excess molar volumes, VmE, were calculated and fitted to the Redlich–Kister equation. The viscosities have also been correlated with several semi-empirical equations. The McAllister equation gives relatively satisfactory results for the correlation.

► Density and viscosity for binary mixtures of tricyclo[5.2.1.02.6]decane with N-methylpiperazine (NMP) or triethylamine (TEA) have been measured at temperature range from 298.15 to 323.15 K.
► All the experimental excess molar volumes, VmE, were calculated and fitted to the Redlich–Kister equation.
► The viscosities have been correlated with five semi-empirical equations.