Thermochemical properties of 1,1-diamino-2,2-dinitroethylene (FOX-7) in dimethyl sulfoxide (DMSO)

The enthalpy of dissolution of 1,1-diamino-2,2-dinitroethylene (FOX-7) in DMSO was measured by means of a RD496-2000 Calvet microcalorimeter at 298.15 K. Empirical formulae for the calculation of the enthalpy of dissolution (ΔdissH), relative partial molar enthalpy (ΔdissHpartial) and relative apparent molar enthalpy (ΔdissHapparent) were obtained from the experimental data of the enthalpies of dissolution of FOX-7 in dimethyl sulfoxide (DMSO). The dilution/crystallization kinetic behavior of FOX-7 in DMSO/water system was investigated and the kinetic equation describing the dilution/crystallization process was presented.