کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
67784 | 48494 | 2007 | 10 صفحه PDF | دانلود رایگان |
The synthesis of a palladium complex and a monosilylated monomer derived from 15-membered azatriolefinic macrocycle are described as well as the preparation of the corresponding hybrid organic–inorganic materials, containing a macrocyclic palladium(0) complex covalently anchored to the silica matrix. The materials were obtained by sol–gel process using different routes: post-synthesis treatment on a mesostructured silica, cogelification of a monosilylated precursor and tetraethylorthosilicate. The activity of the different materials as recoverable catalysts in Suzuki cross-couplings is reported and commented.
Several hybrid organic–inorganic materials containing macrocyclic triolefinic palladium(0) complexes are prepared by sol–gel processes. They are active and reusable catalysts in Suzuki cross-coupling reactions.Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 269, Issues 1–2, 18 May 2007, Pages 204–213