کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
67786 | 48494 | 2007 | 7 صفحه PDF | دانلود رایگان |
Syntheses of a novel family of sulfonamide-based palladium complexes and phenylhydrazine-based palladacycles are described. These catalysts are thermally stable, and not sensitive to air and moisture and some are completely soluble in water. These catalysts have shown excellent activity (good yields and high turnover numbers) and product selectivity in several arylation reactions including Suzuki, Heck, and Sonogashira reactions carried out totally under aqueous conditions.
A novel family of sulfonamide-based palladium complexes and phenylhydrazine-based palladacycles from inexpensive and readily available ligands has been synthesized. These Pd catalysts were used for C–C bond forming reactions such as Suzuki, Heck, Sonogashira reactions and arylation of allyl alcohols in the aqueous medium. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 269, Issues 1–2, 18 May 2007, Pages 218–224