کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7224044 | 1470565 | 2018 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Optical, morphological and structural characterization of Er3 +-Bi3+ co-doped PbS nanocrystals grown by chemical bath
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
PbS nanocrystals co-doped simultaneously in Er3+and Bi3+ solutions were grown and the modification of morphological, structural and some optical properties was investigated. The thicknesses of the undoped and doped PbS films were in the â¼560-400â¯nm range. The morphological changes of the nanocrystals were analyzed using Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM) techniques. Fourier transform infrared spectroscopy ((FT-IR)) spectra showed a broad absorption band located at â¼3500â¯cmâ1 attributed to stretching of the -OH groups and a sharp band at â¼1384â¯cm-1 owing to stretching vibrations mode of CO32- ions. X-ray diffraction displayed a cubic phase in all films and grain size (GS) of the undoped and doped samples were â¼33 and â¼21-17â¯nm, respectively. The films showed stress, a typical behavior of doped nanocrystals displaying residual strain. The absorbance spectra of PbS film exhibited four absorption bands located at â¼251â¯nm (â¼4.9â¯eV), â¼610â¯nm (â¼2.0â¯eV), â¼668â¯nm (â¼1.8â¯eV) and â¼830â¯nm (â¼1.4â¯eV) due to strong confinement effect and â¼446â¯nm (â¼2.7â¯eV), â¼478â¯nm (â¼2.5â¯eV) corresponding to 4F7/2â4I5/2, 4F3/2â4I15/2 (fâf) transitions of Er3+ ions. Sharp bands were found at â¼287 nm (â¼4.3â¯eV) and 366â¯nm (â¼3.38â¯eV), corresponding to transitions of Bi3+ions. The band gap energy of films showed a shift in the â¼0.9-1.2â¯eV range. Raman spectra showed two bands located at â¼450â¯cmâ1 due to the first overtone of the longitudinal optical (LO) phonon (2LO) and a band observed at â¼200â¯cmâ1 which was attributed to the LO (Î) phonon. A kinetic mechanism using the free energy changes Gibbs is proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optik - Volume 162, June 2018, Pages 182-195
Journal: Optik - Volume 162, June 2018, Pages 182-195
نویسندگان
R. Gutiérrez Pérez, O. Portillo Moreno, R. Palomino Merino, L.A. Chaltel Lima, M.N. Márquez Specia, G. Hernández Téllez, E. Rubio Rosas, A. Moreno RodrÃguez,