Estimation of fixed-point temperatures – A practical approach

Phase transition temperatures can be used for thermometer calibrations in accordance with the ITS-90. For this the thermometer is inserted into a fixed-point cell filled with a highly pure substance. While the substance is melting or freezing the temperature inside the cell remains almost constant and the thermometer measures a plateau in the temperature curve. From this plateau the phase transition temperature needs to be estimated for the calibration of the thermometer. This can be done using different mathematical methods, taking into account various systematic deviations as well as reproducibilities of the results depending on the chosen method, the fixed-point material’s purity and above all the amount of fixed-point material. Hence this article presents results from measurements in miniature fixed-point cells filled with zinc of various purities. The plateau curves were measured at different heating rates and comparatively analysed using five different estimation methods.

Research highlights
► We analysed the melting and freezing behaviour of zinc in miniature fixed-point cells.
► On this basis we identified and accordingly enhanced known fixed-point evaluation methods.
► These methods were applied to phase transition curves of miniature fixed-point cells.
► The corresponding results were compared.