کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7744552 | 1498226 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
La2O3-added lithium-ion conducting silicate oxynitride glasses
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Lithium-ion conducting silicate oxynitride glasses of 40Li2O-xLa2O3-(55-x)SiO2-5Si3N4 (mol%) were prepared using melt-quenching method under N2 atmosphere. The doping of La2O3 is aim to improve the electrochemical properties of the silicate oxynitride glasses. The thermal behaviors of the silicate oxynitride glasses were studied by dilatometric and DSC methods. The effects of partial substitution of La2O3 on the thermal, mechanical, chemical and electrical properties of the silicate oxynitride glasses were investigated. The electrical conductivity is in the range of 0.39-1.81â¯Ãâ¯10â6â¯S·cmâ1 at room temperature and 3.54-4.21â¯Ãâ¯10â3â¯S·cmâ1 at 300â¯Â°C, respectively. Moreover, the oxynitride glasses had a high chemical stability to water. The addition of La2O3 to lithium silicate oxynitride glasses improved the ionic conductivity, which has a potential application as Li+ glassy solid electrolyte materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 317, April 2018, Pages 76-82
Journal: Solid State Ionics - Volume 317, April 2018, Pages 76-82
نویسندگان
Zhiwei Luo, Jing Zhang, Jianlei Liu, Jun Song, Anxian Lu,