P-C bond cleavage in dppm derivatives: X-ray structure of [Pd2(μ2-P,C-PPh2CHPOPh2)(μ2-dppm)Cl(PPh2Me)]

► P-C bond cleavage of dppm complex with formation of PPh2Me complex. ► X‐ray structure of one of the few examples of μ2-P,C- coordination of a dppm-H derivative. ► Coexistence of both PPh2Me and μ2-P,C-PPh2CHPOPh2, showing that the former should precede the latter.