کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7824071 | 1502862 | 2018 | 29 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Transparent and soluble polyimide films from 1,4:3,6-dianhydro-D-mannitol based dianhydride and diamines containing aromatic and semiaromatic units: Preparation, characterization, thermal and mechanical properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Transparent and soluble polyimide films from 1,4:3,6-dianhydro-D-mannitol based dianhydride and diamines containing aromatic and semiaromatic units: Preparation, characterization, thermal and mechanical properties Transparent and soluble polyimide films from 1,4:3,6-dianhydro-D-mannitol based dianhydride and diamines containing aromatic and semiaromatic units: Preparation, characterization, thermal and mechanical properties](/preview/png/7824071.png)
چکیده انگلیسی
To develop colorless and soluble polyimide films, a novel dianhydride containing 1,4:3,6-dianhydro-D-mannitol unit, 2,5-bis(3,4-dicarboxyphenoxy)-1,4:3,6-dianhydromannitol dianhydride (IMDA) was synthesized. And two series of polyimides were prepared via a two-step thermal imidization, PIâ(1-4) were obtained from IMDA and four kinds of aromatic diamines while PIâ(5-7) from IMDA and three kinds of semiaromatic diamines. All the polyimides were readily soluble in common polar solvents and could afford flexible, tough and colorless films with transparency up to 89% at 450â¯nm. Especially, polyimides simultaneously containing 1,4:3,6-dianhydrohexitol units in diamine and dianhydride exhibited comparable optical and soluble performance with the alicyclic fluorinated ones. Meanwhile, it was certified that 1,4:3,6-dianhydrohexitol fragment in dianhydride was more determinant in solubility and transmittance of polyimides than that in diamine. An overall investigation of these polyimides on thermal, mechanical, morphological, soluble, optical and dielectric properties was presented, and their structure-property relationships were discussed in detail.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 151, May 2018, Pages 80-89
Journal: Polymer Degradation and Stability - Volume 151, May 2018, Pages 80-89
نویسندگان
Zhiming Mi, Zhixiao Liu, Jianan Yao, Chunbo Wang, Changjiang Zhou, Daming Wang, Xiaogang Zhao, Hongwei Zhou, Yumin Zhang, Chunhai Chen,