Effect of enthalpy of polar modifiers interaction with n-butyllithium on the reaction enthalpy, kinetics and chain microstructure during anionic polymerization of 1,3-butadiene

Evaluation of the influence of polar modifiers forming μ, σ, σ+μ and σ-μ complexes with polymer living center on the interaction enthalpy with n-butyllithium, 1,3-butadiene polymerization enthalpy, polymerization reaction rate and polybutadiene microstructure.114