کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7850603 | 1508849 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen-enriched porous carbon nanosheets with high sodium storage capacity
ترجمه فارسی عنوان
نانو ذرات کربن متخلخل با هیدروژن غنی شده با ظرفیت ذخیره بالا سدیم
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
چکیده انگلیسی
A simple supercritical alcohol route was developed to fabricate hydrogen-enriched porous carbon nanosheets (H-PCNs). The as-prepared H-PCNs were tested as an anode active material for sodium ion batteries. Due to the unique hydrogen donation and alkoxylation ability associated with supercritical isopropanol, the hydrogen-to-carbon ratio of H-PCNs was as high as 2.3. The H-PCNs electrode exhibit an excellent reversible capacity of 300 mAh gâ1 at 50 mA gâ1 and remarkable cycling stability up to 2000 cycles at 1-5 A gâ1. A high rate-performance of 74 mAh gâ1 was also obtained at the high current density of 5 A gâ1. The excellent electrochemical performance of H-PCNs for Na ion uptake is attributed to the high hydrogen-terminated groups and large amount of defects on the carbon sheets. In addition, the large interlayer spacing (0.38 nm), high specific surface area (147 m2 gâ1) and high porosity (58%) would also contribute to the high Na ion uptake.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 98, March 2016, Pages 213-220
Journal: Carbon - Volume 98, March 2016, Pages 213-220
نویسندگان
Dohyeon Yoon, Dong Hyun Kim, Kyung Yoon Chung, Wonyong Chang, Seung Min Kim, Jaehoon Kim,