Effect of phase separation on the Jian ware blue colored glaze with iron oxide

This study was aimed to explore the effect of phase separation on the Jian ware blue colored glaze with iron oxide. In order to analyze the forming cause of glaze patterns and their coloring mechanism, the phase, microstructure and chemical state of the samples were investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectrum. The results indicated that the addition of calcium phosphate introduced highly-active Ca2+ and P5+ into the glaze. Since Ca2+ with high ionic potential had a greater ability to appeal O2− than Si4+, the glaze melt was separated into calcium-rich phase and silicon-rich phase. The difference of viscosity caused the non-uniform distribution of quartz and glass phase, and then affected the distribution of iron ions in two phases, which formed glaze patterns. Adding P5+ that had a strong effect of reversed polarization on the Fe-O increased the contents of Fe2+ and Fe3+-O-Fe2+, and thus deepened the blue-green of glaze surface. In addition, it promoted the formation of worm-like phase-separated structures and the existence of structural color. Therefore, phase separation enriched not only patterns but also glaze colors of the Jian ware blue colored glaze.