کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7967971 | 1514197 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization of 14C in neutron irradiated NBG-25 nuclear graphite
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی هسته ای و مهندسی
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چکیده انگلیسی
Recent studies suggest that the highest concentration of 14C contamination present in reactor-irradiated graphite exists on the surfaces and within near-surface layers. Surface-sensitive analysis techniques (XPS, ToF-SIMS, SEM/EDS and Raman) were employed to determine the chemical nature of 14C on irradiated NBG-25 (nuclear grade) graphite surfaces. Several 14C precursor species are identified on the surfaces of irradiated NBG-25; the quantities of these species decrease at sub-surface depths, which further suggests that 14C formation is predominantly a surface-concentrated phenomenon. The elevated presence of several surface oxide complexes on irradiated NBG-25 surfaces are attributed directly to neutron irradiation. Larger numbers of oxide bonds were found on irradiated NBG-25 surfaces (when compared to unirradiated samples) in the form of interlattice (e.g. ether) and dangling (e.g. carboxylate and ketone) bonds; the quantities of these bond types also decrease with increasing sub-surface depths.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Nuclear Materials - Volume 448, Issues 1â3, May 2014, Pages 113-120
Journal: Journal of Nuclear Materials - Volume 448, Issues 1â3, May 2014, Pages 113-120
نویسندگان
Daniel LaBrier, Mary Lou Dunzik-Gougar,