Nanomechanical characterization of organic matter in the Bakken formation by microscopy-based method

Organic-rich shales are highly heterogeneous due to the presence of a variety of constituent components. Among them, organic matter is poorly known in terms of mechanical properties due to the lack of high-resolution analytical equipment to isolate organic matter in-situ for mechanical testing. In this study, we proposed a new method to link morphology and geochemical properties of organic matter to its mechanical characteristics at the nanoscale. Kerogen type and thermal maturity, along with mineralogy were evaluated by Rock- Eval 6 pyrolysis/Total Organic Carbon (TOC) analysis and X-ray Diffraction (XRD) analysis. Then, the atomic force microscopy PeakForce Quantitative Nano-mechanical Mapping (AFM PeakForce QNM) mode was employed and coupled with optical and electron microscopy, to first visualize and then quantify the elastic properties of organic components in three different samples from the Bakken Formation. Hebamorphinite matrix bituminite and solid bitumen were identified as the main organic constituent, along with oil-prone marine kerogen type II (alginite and acritarch) and also a bacterial-derived granular micrinite-like maceral. Based on Tmax and vitrinite Ro values (or VRo-Eq from Bitumen Ro), thermal maturity of the samples ranged from immature to mature (past peak oil window). The average value of Young's modulus for organic matter was measured in the range of 2.91-11.77 GPa. It was also found that organic matter becomes stiffer with increased thermal maturity. This study exhibits a great potential, as a novel method, for in-situ analysis of mechanical properties of organic matter in shale reservoirs at a fine scale.