کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8948470 | 1645668 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of UC ceramic nuclear fuel microspheres by combination of an improved microwave-assisted rapid internal gelation with carbothermic reduction process
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Uranium carbide (UC) ceramic microspheres filled into a cladding are a potential nuclear fuel format for nuclear reactors. Uniform sized ceramic UC microspheres with a diameter of 675â¯Â±â¯10â¯Âµm were successfully prepared by an improved microwave-assisted rapid internal gelation process combined with carbothermic reduction. First of all, the nanoparticle carbon was dispersed into the HMUR stock solution, and the C-UO3·2H2O gelled microspheres were prepared using an improved microwave-assisted internal gelation process without cooling the initial stock solutions. Next, the gelled microspheres were subjected to a carbothermic reduction process to obtain ceramic UC microspheres. TG and XRD investigations indicated that the C-UO3·2H2O microspheres were firstly reduced into UO2 at a temperature of 700â¯Â°C, and were further converted into UC at 1500â¯Â°C in argon atmosphere. Crack-free ceramic UC microspheres with a smooth and metallic shiny surface were obtained at a sintering temperature of 1500â¯Â°C for 5â¯h with an initial C/U molar ratio of 3.5.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 15, 15 October 2018, Pages 17945-17952
Journal: Ceramics International - Volume 44, Issue 15, 15 October 2018, Pages 17945-17952
نویسندگان
Wei Tian, Hangxu Guo, Desheng Chen, M.A. Pouchon, Alina Horwege, Xiaojie Yin, Qinggang Huang, Jieru Wang, Shiwei Cao, Denglei Chen, Jing Bai, Cunmin Tan, Fangli Fan, Xiaolei Wu, Tielong Shen, Zhi Qin,