کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9760257 | 1498045 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New investigation of fluorine-substituted spinel LiMn2O4âxFx by using sol-gel process
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
To investigate the electrochemical properties of LiMn2O4âxFx (0 < x < 1) as a cathode material for 4-V class lithium secondary batteries, spinel phases synthesized at 800 °C are examined. Although the initial discharge capacity of LiMn2O4 is improved by substitution of Fâ for O2â in the single-phase region, the cycle performance is reduced considerably compared with that of parent LiMn2O4. X-ray diffraction (XRD) data show that the single-phase region of x in LiMn2O4âxFx is 0 < x < 0.2. A secondary phase (Mn2O3) is observed in the region 0.4 < x < 1.0. Voltammetric peaks between 3 and 4.5 V region and XRD data suggest that the oxidation state of Mn in the parent LiMn2O4 increases at the expense of creating second phase (Mn2O3). These results also imply that a second phase spinel can improve the cycling performance of LiMn2O4 by suppressing the Jahn-Teller instability. The oxidation state of Mn in the single-phase spinel and the second-phase coexisting spinel is compared by means of XPS measurements. The electronic conductivity and activation energy of LiMn2O4 is also discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 147, Issues 1â2, 9 September 2005, Pages 220-226
Journal: Journal of Power Sources - Volume 147, Issues 1â2, 9 September 2005, Pages 220-226
نویسندگان
J.T. Son, H.G. Kim,