کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9761727 | 1498426 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Lithium and potassium ion conduction in A3TiBâ²P3O12 (A=Li, K; Bâ²=Zn, Cd) NASICON-type glasses
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Electrical properties of A3TiBâ²P3O12 (A=Li, K; Bâ²=Zn, Cd) NASICON-type glasses are reported over a frequency range from 42 Hz to 1 MHz and at different temperatures. By means of nonlinear least square fitting of the electrical data to appropriate equivalent circuits, the bulk conductivity is separated from electrode effects. The bulk dc conductivity is Arrhenius activated, with activation energies and pre-exponential factors following the Meyer-Neldel rule. The frequency- and temperature-dependent conductivity spectra of individual glasses can be superimposed by means of the Summerfield scaling. However, the master curves of different glasses do not superimpose. We show that this effect is related to the composition dependence of the many-particle displacement function ãR2(t)ã.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 176, Issues 7â8, 28 February 2005, Pages 723-729
Journal: Solid State Ionics - Volume 176, Issues 7â8, 28 February 2005, Pages 723-729
نویسندگان
C.R. Mariappan, G. Govindaraj, B. Roling,