کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1207290 | 1493724 | 2008 | 6 صفحه PDF | دانلود رایگان |
Several sample preparation methods have been assayed to analyze residues of fipronil in honey. After diluting the honey, liquid–liquid extraction (LLE) with organic solvents, and solid-phase extraction (SPE) on commercial cartridges or Florisil-packed column have been tested at three concentration levels: 0.01, 0.1 and 1 mg/kg. LLE with n-hexane or SPE on a Florisil column resulted to be the most suitable procedures to analyze fipronil at trace concentrations. Fipronil was quantified by gas chromatography (GC) with electron-capture detection (ECD) or mass spectrometric (MS) detection after conventional or matrix-matched calibration. The detection limit of fipronil in honey samples was below 1 μg/kg. The degradation of fipronil in honey has also been studied, being identified three minor degradation products in the extracts.
Journal: Journal of Chromatography A - Volume 1187, Issues 1–2, 11 April 2008, Pages 40–45