کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315032 | 976000 | 2010 | 4 صفحه PDF | دانلود رایگان |
The reaction of β-diketiminate substituted germanium(II) and tin(II) fluorides (LGeF (1) and LSnF (2)) (L = CH{(CMe)2(2,6-iPr2C6H3N)2}) with diiron nonacarbonyl, Fe2(CO)9 at room temperature, leads to the iron carbonyl complexes of germanium(II) LGeFFe(CO)4 (3) and tin(II) LSnFFe(CO)4 (4), respectively. Compounds 3 and 4 were characterized by elemental analysis, NMR spectroscopy, and mass spectrometry. Furthermore, both complexes (3 and 4) were investigated by X-ray structural analysis which shows that both compounds are monomeric in the solid state containing terminal fluorine atoms.
The iron carbonyl complexes of germanium(II) fluoride and tin(II) fluoride have been prepared from the corresponding fluoride by the reaction with diiron nonacarbonyl.Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 131, Issue 11, November 2010, Pages 1096–1099