کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315038 | 976000 | 2010 | 11 صفحه PDF | دانلود رایگان |
A series of dibenzo-18-crown-6 lariat ethers containing two C7H15 (11), (CH2)2C6F13 (14), (CH2)2C8F17 (15), NHC7H15 (18) and NHCH2C6F13 (19) sidearms were prepared and the single crystal X-ray structure of cis-4,4′-di(1H,1H,2H,2H-perfluorodecyl)-dibenzo-18-crown-6 (15a) is reported. The “light fluorous” dibenzo-18-crown-6 ether (14) has emerged as a stable and robust PTC catalyst, which can be recycled efficiently by fluorous solid-phase extraction, and gives better PTC catalytic activity compared to the parent, non-fluorinated PTC catalyst, dibenzo-18-crown-6, and the alkylated derivative (11) in aliphatic and aromatic nucleophilic substitutions.
The “light fluorous” crown ether can be recycled efficiently by fluorous solid-phase extraction and it gives better PTC catalytic activity than dibenzo-18-crown-6 in aliphatic and aromatic nucleophilic substitutions.Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 131, Issue 11, November 2010, Pages 1133–1143