کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326151 | 977417 | 2010 | 5 صفحه PDF | دانلود رایگان |
The reactions of oxonium derivatives of [B12H12]2− with different glycerol-based nucleophiles were studied. A series of novel closo-dodecaborate-based glycerols with different net charges on the molecules were prepared. A structure of {2-[2-(4-(2, 3-dihydroxypropyl)-dipiperazinium-1-yl)-ethoxy]-ethoxy}-undecahydro-closo-dodecaborate was determined and the existence of different intermolecular H-bonds was shown.
The reactions of oxonium derivatives of [B12H12]2− with different glycerol-based nucleophiles were studied. A series of novel closo-dodecaborate-based glycerols with different net charges of the molecules were prepared. A structure of {2-[2-(4-(2, 3-dihydroxypropyl)-dipiperazinium-1-yl)-ethoxy]-ethoxy}-undecahydro-closo-dodecaborate was determined and the existence of different intermolecular H-bonds was shown.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 3, 1 February 2010, Pages 370–374