کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1408887 | 1501700 | 2016 | 5 صفحه PDF | دانلود رایگان |
• A (6,3) network is featured with Zn2(COO)3 paddle-wheels.
• The layer structure can be easily exfoliated into isolated sheets in alkaline solution.
• The exclusion of water is crucial to the formation of the target compound.
A metal-organic aggregate, namely {Zn2Cl2(BBC)}n (BBC = 4,4′,4′′-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate) was obtained by solvothermal synthesis. Its structure is featured with the Zn2(COO)3 paddle-wheels with two chloride anions on axial positions and hexagonal pores in the layers. The exclusion of water in the precursor and the solvent plays a crucial role in the formation of target compound. This compound can be easily dissolved in alkaline solution and exfoliated into isolated sheets, which shows a novel way for the preparation of 2D materials.
Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Structure - Volume 1117, 5 August 2016, Pages 135–139