کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1410599 | 1501873 | 2008 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and spectral studies of macrocyclic Cu(II), Ni(II) and Co(II) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and salicylaldehyde derivatives
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and spectral studies of macrocyclic Cu(II), Ni(II) and Co(II) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and salicylaldehyde derivatives Synthesis and spectral studies of macrocyclic Cu(II), Ni(II) and Co(II) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and salicylaldehyde derivatives](/preview/png/1410599.png)
چکیده انگلیسی
Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate. The metal to ligand ratio of the complexes was found to be 1:1. The Cu(II) complexes are proposed to be square planar and the Ni(II) and Co(II) complexes are proposed to be tetrahedral geometry. Macrocyclic complexes are 1:2 electrolytes as shown by their molar conductivities (ÎM) in DMF (dimethylformamide) of 10â3Â M solution. The structure of metal complexes is proposed from elemental analysis, FTIR, UV-vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 891, Issues 1â3, 26 November 2008, Pages 157-166
Journal: Journal of Molecular Structure - Volume 891, Issues 1â3, 26 November 2008, Pages 157-166
نویسندگان
Salih Ilhan, Hamdi Temel,