Encapsulation of ZnO particles by metal fluorides: Towards an application as transparent insulating coatings for windows

Because ZnO is a promising candidate for getting efficient films or varnishes with thermal insulating abilities for windows applications, the effect of the encapsulation of ZnO particles in shells of low refractive index material on the improvement of the visible light transmission was investigated. ZnO–MgF2 core–shell particles were synthesized by deposition of fluoride sols on ZnO particles through a vacuum slip casting process like. The transmission behaviours were first indirectly studied by diffuse reflexion measurements on powder beds. Then, particle films were elaborated by a screen printing process which ensured direct transmission measurements. The encapsulation of ZnO particles with a coating shell of 1.3 wt.% of MgF2 improves the visible light transmission of 32%.

► Doped ZnO oxides exhibit infrared absorption/reflection properties.
► ZnO@MgF2 core–shells are synthesized from fluoride sols and ZnO particles.
► Visible translucent thin films are elaborated by a screen printing process.