کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
38672 45787 2016 10 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
Palladium supported on bis(indolyl)methane functionalized magnetite nanoparticles as an efficient catalyst for copper-free Sonogashira-Hagihara reaction
ترجمه فارسی عنوان
پالادیوم پشتیبانی شده بر روی نانوذرات مگنتیت عاملدار متان بیس (indolyl) به عنوان یک کاتالیزور کارآمد برای واکنش سونوگاشیرا-Hagihara بدون مس
کلمات کلیدی
مغناطیسی؛ پالادیوم؛ نانوذرات سونوگاشیرا؛ بدون مس
Magnetic; Palladium; Nanoparticles; Sonogashira; Copper-free
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• A novel catalyst using Pd supported on bisindolyl functionalized Fe3O4 is synthesized.
• The catalyst was characterized using different analytical methods.
• The catalyst was applied for Sonogashira reactions of aryl halides (Cl, Br, I) under air.
• The Sonogashira reaction was performed under Copper and Phosphane free conditions.
• The catalyst was successfully recycled for seven consecutive runs by an external magnet.

A novel heterogeneous catalyst based on palladium nanoparticles supported on 3,3′-bisindolyl(4-hydroxyphenyl)methane functionalized magnetite (Fe3O4) nanoparticles was synthesized, characterized and used as catalyst for Sonogashira-Hagihara reaction. The alkynylation of a variety of aryl iodides and aryl bromides with terminal alkynes was carried out at 60 °C under copper and phosphane-free conditions using N,N-dimethyl acetamide as solvent, DABCO as base and low Pd loadings (0.18 mol%) under air. In the case of aryl chlorides, the reaction was carried out at 120 °C in the presence of tetra-n-butylammonium bromide (TBAB) and 0.36 mol% of Pd catalyst. The heterogeneous palladium catalyst introduced in this study is recoverable by an external magnet and it can be used for seven consecutive runs without a significant loss in catalytic activity.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 525, 5 September 2016, Pages 31–40
نویسندگان
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