کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5130592 1490842 2017 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reduction of production rate in Y-shaped microreactors in the presence of viscoelasticity
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Reduction of production rate in Y-shaped microreactors in the presence of viscoelasticity
چکیده انگلیسی


- Viscoelasticity effects on reaction-diffusion rates in a Y-microreactor are studied.
- Fluid rheological behavior is assumed to obey the PTT model.
- Finite-volume-based numerical simulations are conducted to handle the problem.
- Viscoelasticity leads to a significant reduction of the production rate.

The viscoelasticity effects on the reaction-diffusion rates in a Y-shaped microreactor are studied utilizing the PTT rheological model. The flow is assumed to be fully developed and considered to be created under a combined action of electroosmotic and pressure forces. In general, finite-volume-based numerical simulations are conducted to handle the problem; however, analytical solutions based on the depthwise averaging approach are also obtained for the case for which there is no reaction between the inlet components. The analytical solutions are found to predict accurate results when the width to height ratio is at least 10 and acceptable results for lower aspect ratios. An investigation of the viscoelasticity effect reveals that it is accompanied by a significant reduction of the production rate and the production efficiency, defined as the ratio of the average product concentration to the inlet concentration of the limiting reactant. In addition, this effect gives rise to a more uniform transport with more symmetric concentration distributions. The pressure effects on the reaction-diffusion rates are also pronounced in the presence of viscoelasticity. Finally, the influences of the product diffusivity are investigated for the first time revealing that the lower it is the thinner the area of significant production becomes.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 990, 16 October 2017, Pages 121-134
نویسندگان
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