کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5139108 | 1494860 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A chemometric cleanup using multivariate curve resolution in liquid chromatography: Quantification of pesticide residues in vegetables
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
Both extraction and chemical cleanup are steps performed when the official AOAC 2007.01 QuEChERS method is used. The chemical cleanup step is required because many co-extractives may still be present after the whole samples extraction; however, it may reduce recovery of certain analytes due to non-selectivity of this step. In addition, unexpected constituents may still interfere with the analysis even when chemical cleanup is carried out, impairing univariate quantification. A chemometric cleanup using MCR-ALS is proposed as an alternative to the QuEChERS chemical cleanup. The performance of the proposed approach was demonstrated through quantification of seven pesticide residues (Carbendazim, Thiabendazole, Fuberidazole, Carbofuran, Carbaryl, 1-naphthol, and Flutriafol) in four non-spiked vegetable samples using HPLC-DAD. With the proposed strategy, it was possible to perform a reliable quantification despite the presence of co-eluted constituents (analytes and interferents), peak shift, band shape changes and avoiding the chemical cleanup with low analyte losses and LOD.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 134, September 2017, Pages 131-139
Journal: Microchemical Journal - Volume 134, September 2017, Pages 131-139
نویسندگان
Emanuella Santos Sousa, Licarion Pinto, Mario Cesar Ugulino de Araujo,